Hexaaquazinc(II) bis[4-(2-hydroxybenzylideneamino)benzenesulfonate]
نویسندگان
چکیده
In the title compound, [Zn(H(2)O)(6)](C(13)H(10)NO(4)S)(2), a distorted ZnO(6) octa-hedron results from the coordination by the six water mol-ecules. Only three of the water molecules are crystallographically unique, as the Zn atom lies on an inversion center. The Zn-O bond lengths are in the range 2.054 (4)-2.073 (4) Å. A network of hydrogen bonds helps to establish the crystal packing.
منابع مشابه
Hexaaquacadmium(II) bis[4-(2-hydroxybenzylideneamino)benzenesulfonate] dihydrate
In the title compound, [Cd(H(2)O)(6)](C(13)H(10)NO(4)S)(2)·2H(2)O, the Cd atom (site symmetry ) adopts a regular octa-hedral coordination and the anion is stabilized by an intra-molecular O-H⋯N hydrogen bond. O-H⋯O hydrogen bonds involving the coordinated and uncoordinated water mol-ecules lead to a three-dimensional network.
متن کاملHexaaquacobalt(II) bis[4-(2-hydroxybenzylideneamino)benzenesulfonate]
In the cation of the title compound, [Co(H(2)O)(6)](C(13)H(10)NO(4)S)(2), the Co atom lies on a centre of symmetry and its coordination geometry is octahedral. The crystal structure is stabilized by water-anion O-H⋯O hydrogen bonds. An intra-molecular O-H⋯N hydrogen bond occurs in the anion.
متن کاملHexaaquanickel(II) bis[4-(2-hydroxybenzylideneamino)benzenesulfonate]
In the title compound, [Ni(H(2)O)(6)](C((C(13) )H(10)NO(4)S)(2), the nickel(II) atom, lying on a center of symmetry, is six-coordinated by six aqua O-atom donors. The dihedral angle between the two benzene rings is 33.1 (3)°. The crystal structure is stabilized by aqua-anion O-H⋯O hydrogen bonds. Intra-molecular O-H⋯N and C-H⋯O hydrogen-bonding inter-actions occur in the anion.
متن کاملHexaaquazinc(II) bis(4-hydroxybenzenesulfonate) dihydrate
In the crystal structure of the title compound, [Zn(H(2)O)(6)](C(6)H(5)O(4)S)(2)·2H(2)O, the Zn(II) atom lies on a center of inversion. The complex cation inter-acts with the anion and uncoord-inated water mol-ecules by O-H⋯O hydrogen bonds, generating a three-dimensional network. The anion is disordered over two equal positions along the hydr-oxy-sulfonate C-C axis.
متن کاملHexaaquazinc(II) dichloride bis(hexamethylenetetramine) tetrahydrate
The title compound, [Zn(H(2)O)(6)]Cl(2)·2C(6)H(12)N(4)·4H(2)O, has been prepared under mild hydro-thermal conditions. The Zn(II) atom, located on a centre of symmetry, is coordinated by six water mol-ecules in a distorted octa-hedral coordination geometry. The hexa-methyl-enetetra-mine mol-ecule is not coordinated to Zn(II) but links the Zn complexes via three O-H⋯N hydrogen bonds. The remainin...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008